Product ID:TRIAD VLC BONDING AGENT
MSDS Date:04/13/1990
FSC:6520
NIIN:01-290-8268
Kit Part:Y
MSDS Number: BJFXD

DENTSPLY/YORK DIV

570 W COLLEGE AVE
YORK, PA 17405
US

Emergency Phone: 717-845-7511

Info Phone: 717-845-7511

Preparer: DON WILSON

Cage: 16969

DENTSPLY/YORK DIV/TRUBYTE DIV

872 YORK, PA 17405-0872 US

Telephone: 717-845-7511

Cage: 16969

METHYL METHACRYLATE (SARA III)

CAS: 80-62-6

RTECS: OZ5075000

Fraction By Weight: 60%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,6-HEXANEDIOL DIMETHYACRYLATE

CAS: 6606-59-3

Fraction By Weight: 10%

TETRAHYDROFURFURYL METHACRYLATE

CAS: 2455-24-5

Fraction By Weight: 30%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO BODY TISSUES
AND MAY EFFECT THE CENTRAL NERVOUS SYSTEM.
Explanation of Carcinogenicity:IARC HAS TESTED METHYL METHYLACRYLATE
AND FOUND EVIDENCE TO BE INCONCLUSIVE.
Effects of Overexposure:EYE:SEVERE IRRITATION. SKIN:IRRITATION,
POSSIBLE DERMATIIS. INHALED: RESPIRATORY IRRITATION, POSSIBLE
HEADACHE,NAUSEA. INGESTED:G/I IRRITATION, POSSIBLE
NAUSEA,VOMITING.
Medical Cond Aggravated by Exposure:NOT GIVEN BY MANUFACTURER.

First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING AS NEEDED.
INGESTED:GIVE 2 LARGE GLASSES OF MILK OR WATER AND IMMEDIATELY
INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET
IMMEDIATE MEDICAL CARE.

Flash Point Method:SCC
Flash Point:=16.1C, 61.F
Lower Limits:2.1
Upper Limits:12.5
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
EXPLOSIVE RUPTURE OF CONTAINERS DUE TO POLYMERIZATION.

Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. EVACUATE
AREA. COVER WITH ADSORBENT & TAKE UP & PLACE IN CLOSED CONTAINER.
VENTILATE AREA & WASH SPILL SITE.
Neutralizing Agent:SMALL QUANTITIES CAN BE REACTED WITH THE APPROPRIATE
HARDENER TO SOLIDIFY.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND
FLAMES. STORE BELOW 100 DEG F IN A DRY, WELL-VENTILATED AREA AWAY
FROM LIGHT. KEEP ORGINAL CONTAINERS TIGHTLY CLOSED.
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. READ MFR'S INSTRUCTIONS AND FOLLOW THEM!!

Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IF EXPOSURE EXCEEDS 100
PPM. SEE 29 CFR 1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR
USE.
Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING
EMISSIONS AT THE POINT OF USE BELOW THE TLV.
Protective Gloves:PVA OR VITON GLOVES RECOMMENDED.
Eye Protection:SAFETY GLASSES OR SPLASH GOGGLES
Other Protective Equipment:NOT GIVEN BY MANUFACTURER. WEAR CLOTHING AS
NEEDED TO MINIMIZE ANY POSSIBLE SKIN CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT.
Supplemental Safety and Health

HCC:F2
Boiling Pt:=100.C, 212.F
Melt/Freeze Pt:=-47.8C, -54.F
Vapor Pres:49
Vapor Density:>1
Spec Gravity:1.08
Evaporation Rate & Reference:3.1
Solubility in Water:1.5% (WT)
Appearance and Odor:CLEAR YELLOW LIQUID
Percent Volatiles by Volume:20%

Stability Indicator/Materials to Avoid:YES
REDUCING AND OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN
FLAMES, STORAGE UNDER INERT ATMOSPHERES.
Hazardous Decomposition Products:NOT GIVEN BY MANUFACTURER, EXPECT
CARBON OXIDES UNDER COMBUSTION CONDITIONS.
Conditions to Avoid Polymerization:ELEVATED TEMPERATURES, SUCH AS IN
FIRE CONDITIONS.

Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER SUGGESTS THAT DISPOSAL MAY BE DONE BY
LANDFILL. DO NOT PERMIT TO ENTER SEWER OR ANY WATERWAY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.